Hello @Jan Didden ,
Yes, A default OU for AADDC Users is created that contains all the synchronized user accounts from your Azure AD tenant. You can't add/move users or groups from the AADDC Users OU to custom OUs that you create. Only user accounts or resources created can be created in Custom OU's also users/groups can be moved between custom OUs.
To learn more about how to create an Organizational Unit (OU) in an Azure Active Directory Domain Services managed domain.