Hi @Luiz Soares , one possible reason for this error is that the user account you are trying to invite may not exist in Azure AD. The administrator of the tenant where the user account belongs may have a policy in place preventing users from being created. The user must check with their admin to determine if external users are allowed. The external users admin may need to allow Email Verified users in their domain.
Another possible reason for this error is that the user account you are trying to invite may already exist in Azure AD. In this case, you can try to search for the user in the Azure AD portal and add them to your directory instead of sending an invitation.
Please check these and let me know if it solves your problem. If not I can help you further.
If this answer helps you please mark "Accept Answer" so other users can reference it.
Thank you,
James