Hey,
Check if you have configured permissions on your LUN on Synology.
https://kb.synology.com/tr-tr/DSM/tutorial/How_can_I_troubleshoot_iSCSI_connection_issues_7
If you have configured mutual chap, you should configure it separately.
https://slice2.com/wp-content/uploads/2013/06/configuring-mpio-and-iscsi-mutual-chap-on-windows-v1.pdf
Might also help: https://www.starwindsoftware.com/blog/secure-your-data-for-good-with-challenge-handshake-authentication-protocol
You can also check configuration with a different iSCSI target. StarWind VSAN can be used as an alternative. https://www.starwindsoftware.com/starwind-virtual-san
Cheers,
Alex Bykovskyi
StarWind Software
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