after it is synced to Azure AD
What does this mean? After "what" is synced to AAD? And synced from "where"?
Enrolling in Intune has nothing to do with your on-prem AD -- they are completely unrelated and independent.
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Can we enroll Windows 10 laptops after it is synced to Azure AD and will it show in onprem AD under devices as currently they are not in our domain joined and they are in workgroup?
after it is synced to Azure AD
What does this mean? After "what" is synced to AAD? And synced from "where"?
Enrolling in Intune has nothing to do with your on-prem AD -- they are completely unrelated and independent.