Hi @JH ,
MFA verification options can be set per tenant and will be the same for all users that are enabled for MFA.
I don't see anywhere in Azure docs that you can have different MFA verification options for different users.
To set MFA verification options or enable/disable users for MFA you can go to following link:
https://account.activedirectory.windowsazure.com/UserManagement/MfaSettings.aspx
And any CA you set will apply on top.
Hope this helps!