Hi @GoodResource ,
Do you want to Choose which folder to sync in OneDrive? If yes, you can refer to this article:
https://www.ubackup.com/windows-10/sync-local-folder-to-onedrive.html
Note: Microsoft is providing this information as a convenience to you. The sites are not controlled by Microsoft. Microsoft cannot make any representations regarding the quality, safety, or suitability of any software or information found there. Please make sure that you completely understand the risk before retrieving any suggestions from the above link.
What's the meaning of "Can we login, activate and sync OneDrive on user's behalf."? Do you want to login, activate and sync with Administrator account?
Try to provide more information about this problem and I'm glad to help you.
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